56 Best Chemicals Used in Pulp & Paper Mills (Tried & Tested)

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Written By World Paper Mill

Pulp and Paper Industry Expert

Looking for a list of chemicals used in pulp and paper making?

You’re at the right place!

We assume you are known to the fact that a large number of adhesives and chemicals are used in pulp and paper making.

Paper is a generic term that includes the presence of a broad range of substances within it. These substances that are present in the paper come with various textures and coatings.

Now, many of these substances are adhesives and chemicals.

Each adhesive and chemical that is added to the pulp slurry while making paper holds unique properties to give a specific purpose to the paper.

Adhesives are added for giving stickiness property to the material to keep it together.

Adhesives are responsible for holding the slurry together.

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They create bonds between the pulp particles and make them stick to each while providing strength to the material.

These adhesives are available in different types such as natural, synthetic, semi-synthetic, etc.

Chemicals are substances with unique molecular composition.

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The chemicals are responsible for providing the required qualities to the paper.

Different types of chemicals are added to the pulp to provide different properties to the pulp. Chemicals are categorized into types like brightening agents, sizing agents, pigments, fillers, etc.

Here, we are going to share with you the list of 56 important chemicals used in pulp and paper making along with their formula and properties –

1. Agalite or Talc

Chemical name: Silicate of Magnesia

Formula: MgO-32%, SiO2-42%

Purpose: It helps to provide a greasy/soapy feel to the paper. It also improves the finishing

2. AKD

Chemical name: Alkyl Ketene Dimer

Formula: C4H4O2

Purpose: Sizing Agent

3. Alabaster or Annaline

Chemical name: Anhydrate Calcium Sulfate

Formula: CaSO4

Purpose: Paper loading material

4. Alganic Acid

Chemical name: Alganic acid or Na-Alginate

Formula: Na-(C6H8O6)n

Purpose: Used for coating and surface treatment

5. Alum

Chemical name: Sulfate of Alumina

Formula: Al2(SO4)3.18H2O

Purpose: For alkaline sizing along with Rosin

6. Albarine

Chemical name: Natural Sulfate of Lime

Formula: CaSO4.2H2O – 100%

Purpose: It is a calcium salt that is used for a variety of purposes including building materials

7. Animal Glue

Purpose: It is a pigment coating Binder

8. Barium Carbonate

Chemical name: Barium Carbonate

Formula: BaCO3

Purpose: Used as a coating pigment

9. Blanc fix, fast white, pearl white or permanent white

Chemical name: Barium Sulfate

Formula: BaSO4

Purpose: Used as a filler or also a coating pigment

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10. Casein

Chemical name: Casein

Purpose: It is a pigment coating binder. Casein is a heterogeneous globular, amphoteric phosphoprotein

11. Chlorine Dioxide

Chemical name: Chlorine Dioxide

Formula: ClO2

Purpose: Used in Pulp Bleaching

12. Chlorine Gas

Chemical name: Chlorine

Formula: Cl2

Purpose: Used in pulp bleaching and water treatment

13. Clay or Kaolin

Chemical name: Kaolinite

Formula: Al2Si2O5(OH)4

Purpose: Used as a filler

14. Dolomite

Chemical name: Calcium Magnesium Carbonate

Formula: CaMg(CO3)2

Purpose: Filler, Coating

15. DTPA

Chemical name: Diethylene Triamine Penta Acetate

Formula: C14H33N3O10

Purpose: Used for chelation i.e. removal of transition metals from pulp

16. EDTA

Chemical name: Ethylene Diamine Tetra acetic Acid

Formula: C10H16N2O8

Purpose: Used for chelation i.e. removal of transition metals from pulp

17. Enzyme

Purpose: Used in Deinking

18. FSA

Chemical name: Formamidine Sulphuric Acid or Thiourea Dioxide

Formula: CH4N2SO2

Purpose: Post Deinking bleaching

19. Guar Gum

Chemical name: Natural Polymer

Purpose: It is a Dry Strength Additive

20. Gypsum or Mineral White or Plaster

Chemical name: Natural Sulfate of Lime

Formula: CaSO4.2H2O

Purpose: Gypsum board

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21. Hydrogen Peroxide

Chemical name: Hydrogen Peroxide

Formula: H2O2

Purpose: Used in Bleaching

22. Hypochlorous Acid

Chemical name: Hypochlorous Acid

Formula: HOCl

Purpose: Used In Pulp Bleaching

23. Lime

Chemical name: Calcium Oxide

Formula: CaO

Purpose: Alkaline Pulping Process Chemical Recovery, Bleaching

24. Lime Stone

Chemical name: Calcium Carbonate

Formula: CaCO3

Purpose: To make Precipitated CaCO3, is used as Filler and in Coating

25. Magnesium Bisulfite

Chemical name: Magnesium Bisulfite

Formula: Mg(HSO3)2

Purpose: Used in Sulfite pulping

26. Magnesite

Chemical name: Magnesium Carbonate

Formula: MgCO3 -100%

Purpose: Filler for cigarette paper

27. Milk of Lime

Chemical name: Calcium Hydroxide

Formula: Ca(OH)2

Purpose: For causticizing of green liquor

28. Milk of Magnesia

Chemical name: Magnesium Hydroxide

Formula: Mg(OH)2

29. Oxygen

Chemical name: Oxygen

Formula: O2

Purpose: Used in Bleaching

30. Ozone

Chemical name: Ozone

Formula: O3

Purpose: In Pulp Bleaching

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31. Polyvinyl Alcohol (PVA)

Chemical name: Polyvinyl Alcoho

Formula: [CH2CH(OH]n

Purpose: It is a Pigment coating Binder

32. Rosin

Chemical name: Abietic Acid

Formula: C19H29COOH

Purpose: It is a Sizing Agent

33. Rosin Soap

Chemical name: Sodium Abietate

Formula: C19H29COONa

Purpose: It is a Sizing Agent

34. Salt Cake

Chemical name: Sodium Sulfate

Formula: Na2SO410H2O

Purpose: It is a makeup chemical used in sulfate pulping chemical recovery (Na2SO4. —Na2S)

35. Satin

Formula: 3CaO.Al2O3.3CaSO4.31H2O

Purpose: It is a bright white pigment

36. Soap/ Fatty Acid

Purpose: Used in Deinking

37. Sodium Bisulfite

Chemical name: Sodium Bisulfite

Formula: NaHSO3

Purpose: Used in Sulfite pulping

38. Soda Ash

Chemical name: Sodium Carbonate

Formula: NaHSO3

Purpose: It is used as a makeup chemical in alkaline pulping chemical recovery (Na2CO3 +Ca(OH)2—2NaOH+CaCO3)

39. Sodium Aluminate

Chemical name: Sodium Aluminate

Formula: Na2Al2O4

Purpose: Used in conjunction with alum to control pH

40. Sodium Bisulfite

Chemical name: Sodium Bisulfite

Formula: NaHSO3

Purpose: An acid type cooking liquor chemical component sometimes used to neutralize residual chlorine in the pulp during the bleaching process

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41. Sodium Chlorate

Chemical name: Sodium Chlorate

Formula: NaClO3

Purpose: Used to generate Chlorine Dioxide

42. Sodium Dithionite

Chemical name: Sodium Hydrosulfite

Formula: Na2S2O4

Purpose: Bleaching

43. Sodium Hypo-chlorite

Chemical name: Sodium Hypo-chlorite

Formula: Na2S2O4

Purpose: Bleaching

44. Sodium Peroxide

Chemical name: Sodium Peroxide

Formula: Na2O2

Purpose: Bleaching

45. Sodium Silicate

Chemical name: Sodium Silicate

Formula: Na2SiO3

Purpose: In waste paper deinking for wetting, peptization, ink dispersion, peroxide stabilization.

46. Sodium Sulfide

Chemical name: Sodium Sulfide

Formula: Na2S

Purpose: Active chemical in kraft/sulfate cooking liquor

47. Sodium Thiosulfate

Chemical name: Sodium Thiosulfate

Formula: Na2S2O3

Purpose: Bleaching

48. Sodium tripolyphosphate

Chemical name: Sodium tripolyphosphate

Formula: Na5P3O10

Purpose: Dispersant

49. Starch

Chemical name: Starch

Purpose: Comprised of glucose units linked together by oxygen bridges called glycosides. It is a wet and dry end additive

50. Sulfur

Chemical name: Sulfur

Formula: S

Purpose: To make HSO3 for bisulfite pulping

51. Surfactant

Purpose: Used in deinking, Used as de-bonders in fluff pulp manufacture.

52. Titania

Chemical name: Titanium Dioxide

Formula: TiO2

Purpose: Used as a filler to increase the opacity and brightness of paper as well as also used in coating purpose

53. Anatase

Chemical name: Titanium Dioxide

Formula: TiO2

Purpose: Grade of titanium oxide paper coating pigments which is water dispersible

54. Zinc Hydrosulfite

Chemical name: Zinc Hydrosulfite

Formula: ZnS2O4

Purpose: Bleaching Chemical

55. Zinc Sulfide

Chemical name: Zinc Sulfide

Formula: Formula: ZnS

Purpose: Pigment

56. Zinc White

Chemical name: Zinc Oxide

Formula: ZnO

Purpose: Pigment

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